澳门在线威尼斯官方-威尼斯威尼斯国际网址

澳门在线威尼斯官方
师资力量

余达刚     教授、博士生导师

研究方向:绿色有机合成化学(二氧化碳利用、可见光催化);过渡金属催化方法学(铜、铁等低价金属催化)

联系方式:028-85470816          Email:yudagang86@163.com (优先);dgyu@scu.edu.cn

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简历

余达刚博士,男,1986年9月出生于江西奉新。

学习经历

2003.09—2007.07 澳门在线威尼斯官方读本科,导师:冯小明教授,袁立华教授

2007.09—2012.07北京大学化学与分子工程学院有机化学专业攻读博士学位,导师:施章杰教授

工作经历

2012.10—2014.12  德国明斯特大学进行博士后研究,洪堡学者,导师:Prof. Frank Glorius

2015.01至今       澳门在线威尼斯官方从事教学和科研,教授, 博士生导师

主要研究方向

主要研究方向

绿色有机合成化学(二氧化碳利用、可见光催化)

过渡金属催化方法学(铜、铁等低价金属催化)

功能分子构建新方法研究(重要杂环、羧酸合成)

诚招副研究员、博后、研究助理、硕博生以及交流生

http://www.x-mol.com/recruitment/job/32196

主要工作业绩

主要工作业绩

二氧化碳(CO2)作为空气中的重要组分,也是广泛存在、低价易得、无毒、稳定、可再生循环使用的碳一C1)资源。由于CO2在热力学和动力学方面有较高的稳定性,反应活性较低,CO2活化具有巨大的挑战。2015年余达刚博士独立建组以来,坚持围绕CO2活化与转化的基本科知识题开展独特研究,发展了CO2高效活化与选择性转化的新理念、新策略和新反应,具体如下:

针对碳氢键氧化羰基化反应中存在的问题(需要使用剧毒的CO和当量的氧化剂),大家首次提出“CO2 = CO + [O]”理念,利用CO2代替CO和氧化剂参与碳氢键羰基化反应,发展了近十类重要含羰基杂环类化合物的高效合成方法,提出了新反应机制,不仅变废为宝,还降低成本,提高安全性,具有较强的实用性;基于过渡金属催化和可见光催化策略,大家发展了自由基型CO2转化模式,一方面通过调控自由基参与不饱和烃转化反应的选择性,在室温常压下实现了噁唑啉酮和多种类型羧酸的高效制备,另一方面基于可见光促进单电子活化策略,通过单电子还原CO2或烯烃形成自由基负离子,实现了具有独特区域选择性的烯烃羧基化反应;基于极性翻转策略,大家通过惰性化学键(如碳氟键和碳氮键)的选择性断裂实现了CO2参与的羧基化反应;此外,大家首次实现了铜催化CO2参与的芳基烯烃和1,3-二烯的不对称还原羟甲基化反应,取得了优秀的对映选择性、化学选择性、区域选择性和Z/E选择性,高效构建了具有手性(季碳)中心的高苄醇和高烯丙醇。这些工作实现了CO2的变废为宝和高附加值产品的精准合成,为研究CO2活化的本质和规律提供了新的实验基础和理论模型,为促进我国CO2化学研究起了积极的作用。

独立工作以来,余达刚博士以通讯编辑身份在J. Am. Chem. Soc.Angew. Chem. Int. Ed.Nature   Commun.,《中国科学-化学》和《中国化学》等学术刊物上发表学术论文37篇,其中有多篇论文成为相应期刊封面、扉页文章、VIP和当月下载量前列的文章,多篇被ChemistryViewsSynfactsOrganic Chemistry   PortalOPR&D和《有机化学》作为亮点先容。此外,在国内外学术会议、大学和企业做了50余次报告,其中包括2018国际配位化学会议二氧化碳化学专场上主题报告。此外,他还作为共同客座编辑组织《中国化学》的二氧化碳化学专辑和Green Chemistry “CO2 Utilization”专辑。

 

主要奖励和荣誉

2018年中国化学会青年化学奖

2018年国家自然科学基金委优秀青年基金

2018年霍英东青年教师基金

2018年澳门在线威尼斯官方优秀教师

2017 ACP Lectureship Awards to Japan

2017 Thieme Chemistry Journal Award

2017年澳门在线威尼斯官方优秀本科毕业论文二等奖引导教师

2016年澳门在线威尼斯官方青年科技人才奖

2016届优秀本科毕业论文一等奖引导教师

2013-2014年德国洪堡奖学金

2013Reaxys PhD Prize (Finalist)

2012年陶氏化学可持续发展创新奖(特等奖)

2012年北京大学“学术十杰”

2012年北京大学化学与分子工程学院优秀博士论文

2011SciFinder Recognition in Excellence   Program for OMCOS16

2011年北京大学化学与分子工程学院“化学之星”二等奖

2010年北京大学“三好学生”             

2010年北京大学“常青特等奖学金”    

2009年北京大学“常青一等奖学金”       

 

学术报告

1.    2019年第二届国际有机光化学合成论坛,南昌,20191123

2.    江西师范大学化学学院,南昌,20191122

3.    第一届全国二氧化碳资源化会议,天津,20191110

4.    清华大学化学系, 北京, 20191031

5.    1st International Green and Sustainable   Chemistry Conference,北京,20191018

6.    中国化学会第十六届均相催化学术会议,武汉,2019927

7.    中国化学会第十一届全国有机化学学术会议,上海,201992

8.    德国雷根斯堡大学,20190704

9.    德国海德堡大学,20190702

10.   德国明斯特大学,20190701

11.   德国哥廷根大学,20190628

12.   The 17th International Conference on Carbon   Dioxide Utilization,德国亚琛,20190626

13.   德国亚琛工业大学,20190625

14.   第十五届中美化学教授会议,新乡,20190618

15.   澳门在线威尼斯官方博士后交叉学科论坛,成都,2019426号。

16.   International Symposium on Radical Chemistry, 福建物构所,福州,2019416号。

17.   第二届全国有机自由基化学会议,南方科技大学,深圳,2019413号。

18.   华中师范大学有机光化学合成论坛,武汉,20181127号。

19.   第二十届全国金属有机化学学术讨论会,南京,2018113号。

20.   第一届全国光功能材料青年学者研讨会会议,昆明,2018916号。

21.   The 43rd International Conference on   Coordination Chemistry (ICCC),日本仙台,201884号。

22.   北海道大学,日本札幌,2018730号。

23.   东京工业大学,日本东京,2018727号。

24.   RIKEN,日本东京,2018726号。

25.   京都大学,日本京都,2018724号。

26.   大阪大学,日本大阪,2018723号。

27.   第三届齐鲁有机论坛,山东大学,济南,2018615号。

28.   中国化学会第31届学术年会,杭州,201856号。

29.   华中师范大学,武汉,2018424号。

30.   南开大学,天津,2018411号。

31.   第十届全国有机化学学术会议,深圳,20171217号。

32.   空气中关键组分的活化及利用研讨会,新昌,2017129号。

33.   The 12th International Conference on   Cutting-Edge Organic Chemistry in Asia (ICCEOCA-12),西安,2017114号。

34.   第十二届全国物理有机化学学术会议,武汉,20171017号。

35.   International Symposium on Organic Chemistry in   Western China, Chengdu, 10/08/2017

36.   第十五届全国均相催化学术讨论会,杭州,2017927号。

37.   第十五届全国光化学学术讨论会,兰州,2017823号。

38.   19th IUPAC International Symposium on   Organometallic Chemistry Directed Towards Organic Synthesis (OMCOS19), 韩国济州,2017627号。

39.   教育部“春晖计划”德国专家工作团西南石油大学交流研讨会,   2017417号。

40.   江西同和药业企业,奉新,2017124号。

41.   四川师范大学双一流系列学术报告,成都,20161216号。

42.   Tateshina Conference on Organic Chemistry 2016,   Tateshina, 20161110号。

43.   第十九届全国金属有机化学学术讨论会,杭州,20161030号。

44.   2016年纳米催化和清洁合成学术研讨会,苏州,20161029号。

45.   2016 International Symposium on C-O Activation,   Himeji, 20161027号。

46.   The 12th International Symposium on Organic Free   Radicals,上海,2016911号。

47.   2016西部有机化学论坛,成都,201685号。

48.   中国化学会第30届学术年会,大连,201672号。

49.   12届中美化学华人教授会议,广州,2016625日。

50.   中国化学会第九届全国有机化学学术会议,长春,2015729日。

51.   11届中美化学华人教授会议,苏州,2015623日。

52.   中国工程物理研究院材料所,江油,2015424日。

53.   第七届中德华人教授论坛,明斯特,德国,2015418号。

54.   2014 Reaxys Inspiring Chemistry Conference,   Grindelwald,瑞士,2014922号。

55.   2nd International Symposium on C-H ActivationRennes,法国,201472号。

56.   留德华人化学化工学会北威州分会(GCCCD-NRW)第7 届学术年会,波鸿,德国,2014517号。

57.   中国化学会留德华人化学化工学会(GCCCD)第25 届学术年会,杜伊斯堡,德国,201397号。

58.   第四届“CCME-IOC & ICCAS-LMRFAlfa   Aesar 研究生学术研讨会,2011218号。

代表性成果 (获奖成果、专著、论文、专利)


1.     X.-W. Chen, L. Zhu, Y.-Y.   Gui, K. Jing, Y.-X. Jiang, Z.-Y. Bo, Y.   Lan,* J. Li, D.-G. Yu*, Highly   Selective and Catalytic Generation of Acyclic Quaternary Carbon Stereocenters   via Functionalization of 1,3-Dienes with CO2. J. Am.   Chem. Soc. 2019, 141, 18825. (Highlighted   by ChemBeanGo and Chin. J. Org. Chem. 2020,   40, 247)

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2.   M. Miao, L.-L. Liao, G.-M.   Cao, W.-J. Zhou,* D.-G. Yu*, Visible-light-mediated external-reductant-free reductive   cross coupling of benzylammonium salts with (hetero)aryl nitriles.   Sci. China Chem. 2019, 62, 1519. (Invited Contribution to SPECIAL   ISSUE: Organic Free Radical Chemistry)

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3.    Z. Zhang, L. Gong, X.-Y.   Zhou, S.-S. Yan, J. Li*, D.-G. Yu*, Radical-Type Difunctionalization of Alkenes with CO2.   Acta Chim. Sinica 2019, 77, 783 (Invited Contribution to SPECIAL ISSUE: Organic Radical   Chemistry)

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4.   Q. Fu, Z.-Y. Bo, J.-H. Ye,   T. Ju, H. Huang, L.-L. Liao, D.-G.   Yu*, Transition metal-free phosphonocarboxylation of alkenes   with carbon dioxide via visible-light photoredox catalysis. Nat.   Commun. 2019, 10, 3592.

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5.  S.-S. Yan, D.-S. Wu, J.-H.   Ye, L. Gong, X. Zeng, C.-K. Ran, Y.-Y. Gui, J. Li, D.-G. Yu*, Copper-Catalyzed Carboxylation of C?F Bonds with CO2. ACS Catal. 2019, 9, 6987. (Highlighted by Synfacts   2019, 15, 1159)

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6.   W.-J. Zhou,* G.-M. Cao,   Z.-P. Zhang, and D.-G. Yu*, Visible Light-Induced Palladium-Catalysis in Organic   Synthesis. Chem. Lett. 2019, 48, 181. (Invited   Contribution. Cover)

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7.   Y. Chen*, L.-Q. Lu*, D.-G. Yu*, C.-J.   Zhu* and W.-J. Xiao*, Visible light-driven organic photochemical synthesis in   China. Sci. China Chem. 2019, 62, 24. (Invited   Contribution)

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8.    L.-L. Liao, G.-M. Cao, J.-H.   Ye, G.-Q. Sun, W.-J. Zhou, Y.-Y. Gui, S.-S. Yan, G. Shen, D.-G. Yu*, Visible-light-Driven   External-Reductant-Free Cross-Electrophile Couplings of Tetraalkyl Ammonium   Salts. J. Am. Chem. Soc. 2018, 140, 17338. (Top 1   most read JACS papers in December, 2018.)

 

9.  T. Ju, Q. Fu, J.-H. Ye, Z.   Zhang, L.-L. Liao, S.-S. Yan, X.-Y. Tian, S.-P. Luo, J. Li, D.-G. Yu*, Selective   and Catalytic Hydrocarboxylation of Enamides and Imines with CO2   to Generate α,α-Disubstituted α-Amino Acids. Angew. Chem. Int. Ed. 2018,   57, 13897.

 

10.  S.-S. Yan, Q. Fu, L.-L.   Liao, G.-Q. Sun, J.-H. Ye, L. Gong, Y.-Z. Bo-Xue, D.-G. Yu*, Transition   metal-catalyzed carboxylation of unsaturated substrates with CO2. Coord.   Chem. Rev. 2018, 374, 439. (Invited Contribution)

 

11.  W.-J. Zhou,*? Yi-Han Zhang,? Y.-Y. Gui, L. Sun, D.-G. Yu*, Merging Transition Metal-Catalysis with Photoredox Catalysis: A   Environmentally Friendly Strategy for C-H Functionalization. Synthesis 2018, 50, 3359. (? Equal contribution. Invited   Contribution to the Special Issue on “Photocatalysis”)

12.  L. Song, L. Zhu, Z.   Zhang, J.-H. Ye, S.-S. Yan, J.-L. Han, Z.-B. Yin, Y. Lan*, D.-G. Yu*, Catalytic   Lactonization of Unactivated Aryl C─H Bonds with CO2: Experimental   and Computational Investigation. Org. Lett. 2018, 20, 3776. (Top 14 most read papers in July, 2018)

13. Z. Zhang,*?   J.-H. Ye,? D.-S.   Wu, Y.-Q. Zhou, D.-G. Yu*, Synthesis   of Oxazolidin-2-ones from Unsaturated Amines with CO2 via   Homogeneous Catalysis. Chem.   Asian J. 2018, 13,   2292. (? Equal   contribution. Invited Contribution to the Special Issue on “Homogeneous   Catalysis from Young Investigators in Asia”)

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14.  L. Song, G.-M. Cao, W.-J. Zhou, J.-H.   Ye, Z. Zhang, X.-Y. Tian, J. Li, D.-G. Yu*, Pd-catalyzed   carbonylation of aryl C─H bonds in benzamides with CO2. Org. Chem. Front. 2018,   5, 2086. (Invited Contribution to the Special Issue on “Celebrating the 90th birthday of Professor Lu   Xiyan”)

15.   G. Shen,   W.-J. Zhou*, X.-B. Zhang, G.-M. Cao, Z. Zhang, J.-H. Ye, L.-L. Liao, J. Li, D.-G. Yu*, Synthesis of tetronic acids from   propargylic alcohols and CO2. Chem. Commun.   2018, 54, 5610.

16.   S.-S. Yan,   L. Zhu, J.-H. Ye, Z. Zhang, H. Huang, H. Zeng, C.-J. Li*, Y. Lan*, D.-G. Yu*, Ruthenium-catalyzed umpolung carboxylation of hydrazones with CO2. Chem. Sci. 2018,   9, 4873. (Highlighted by CBG.)

17.   L. Sun, J.-H. Ye,   W.-J. Zhou*, X. Zeng, D.-G. Yu*, Oxy-Alkylation of Allylamines   with Unactivated Alkyl Bromides and CO2 via Visible-Light-Driven   Palladium Catalysis. Org. Lett. 2018, 20,   3049. (Top 8 most read papers in May, 2018. Highlighted by CBG.)

18.   Z. Zhang*,   C.-J. Zhu, M. Miao, J.-L. Han, T. Ju, L. Song, J.-H. Ye,   J. Li, D.-G. Yu*, Lactonization of C(sp2)─H   Bonds in Enamides with CO2. Chin. J. Chem.   2018, 36, 430. (Cover. Invited Contribution to the Special   Issue on “CO2 chemistry”)

19.     Z.-B. Yin,? J.-H.   Ye,? W.-J. Zhou, Y.-H. Zhang, L. Ding, Y.-Y. Gui, S.-S. Yan, J.   Li, D.-G. Yu*, Oxy-Difluoroalkylation   of Allylamines with CO2 via Visible-Light Photoredox Catalysis. Org. Lett. 2018, 20, 190. (? Equal   contribution. ESI高被引论文)

20.   Y.-Y. Gui,   Z.-X. Wang, W.-J. Zhou*, L.-L. Liao, L. Song, Z.-B. Yin, J. Li, D.-G. Yu*, Arylation of Aniline C(sp3)─H   Bonds with Phenols by an in-situ Activation Strategy. Asian   J. Org. Chem. 2018, 7, 537. (Selected as Cover and VIP. Highlighted   by ChemistryViews. Invited paper for the Special Issue on   Early Career Researchers in China)

21.     L. Zhu, J.-H. Ye, M. Duan, X.   Qi, D.-G. Yu*, R. Bai*, Y. Lan*, On the Mechanism of Copper-Catalyzed Oxytrifluoromethylationof   Allylamines with CO2: A Computational Study.  Org.   Chem. Front. 2018, 5,   633. (ESI高被引论文)


22.     X. Yan, H. Sun, H. Xiang, D.-G. Yu, D. Luo, X. Zhou,* Palladium-Catalyzed C(carbonyl) –C Bond   Cleavage of Amides: A Facile Access to Phenylcarbamate Derivatives with   Alcohols. Chem. Commun. 2018, 54, 8606.

23.     Y.-Y. Gui,? N.   Hu,? X.-W. Chen, L.-L. Liao, T. Ju, J.-H. Ye, Z. Zhang, J. Li, D.-G.   Yu*, Highly   Regio- and Enantioselective Copper-Catalyzed Reductive Hydroxymethylation of   Styrenes and 1,3-Dienes with CO2. J. Am. Chem. Soc. 2017,   139, 17011. (? Equal contribution. Cover. Top 4 most read JACS   papers in November, 2017. Highlighted by Synfacts 2018, 14,   0177, CJOC, X-MOL, OPR&D and Organic Chemistry Portal)

 

24.     J.-H. Ye, M. Miao, H. Huang, S.-S. Yan, Z.-B. Yin, W.-J. Zhou, D.-G. Yu*,   Visible light-driven   and Iron-promoted Thiocarboxylation of Styrenes and Acrylates with CO2. Angew. Chem. Int. Ed. 2017,   56, 15416. (Top 11 most accessed papers in November, 2017. Highlighted   by X-MOL)

 

25.     W.-J. Zhou, G.-M. Cao, G.   Shen, X.-Y. Zhu, Y.-Y. Gui, J.-H. Ye, L. Sun, L.-L. Liao, J. Li,   D.-G. Yu*, Visible-Light-Driven   Pd-Catalyzed Radical Alkylation of C─H Bonds with General Unactivated Alkyl   Bromides. Angew. Chem. Int. Ed. 2017, 56,   15683. (Top 2 most accessed papers in November, 2017. Highlighted by X-MOL)

26.     J.-H. Ye,? L.   Zhu,? S.-S. Yan, M. Miao, X.-C. Zhang, W.-J. Zhou, J.   Li, Y. Lan*, D.-G. Yu*, Radical   Trifluoromethylative Dearomatization of Indoles and Furans with CO2.   ACS Catal. 2017, 7, 8324. (? Equal   contribution. Top 6 most read papers in November, 2017.)

27.   Y.-Y. Gui, X.-W.   Chen, W.-J. Zhou*, D.-G. Yu*, Arylation of Amides and Ureas   C(sp3)─H Bonds with Aryl Tosylates via   in situ Generation from Phenols. Synlett 2017,   28, 2581. (Cover. Invited paper for the issue of C-O activation)

 

28.   L.-L. Liao,   Y.-Y. Gui, X.-B. Zhang, G. Shen, H.-D. Liu, W.-J. Zhou, J. Li, D.-G. Yu*, Phosphorylation of Alkenyl and   Aryl C─O Bonds via Photoredox/Nickel Dual Catalysis. Org. Lett. 2017,   19, 3735. (Top 2 most read papers in July, 2017)

29.   周文俊*,张逸寒,曹光梅,刘惠东,余达刚*钯催化卤代烷烃参与的自由基型转化反应有机化学201737, 1322。(应邀综述

30.   Y.-Y. Gui?,   W.-J. Zhou?, J.-H. Ye, D.-G. Yu*, Photochemical Carboxylation of Activated C(sp3)─H   Bonds with CO2. ChemSusChem 2017,   10, 1337. (? Equal   contribution. Highlight)

 

31.   Z. Zhang,   T. Ju, J.-H. Ye, D.-G. Yu*, CO2 = CO + O:   Redox-neutral Lactamization and Lactonization of C─H Bonds with CO2.Synlett 2017,   DOI: 10.1055/s-0036-1588403. (Invited Synpacts paper)

 

32.   Z. Zhang?, T. Ju?, M. Miao,   J.-L. Han, Y.-H. Zhang, X.-Y. Zhu, J.-H. Ye, D.-G. Yu*, Y.-G.   Zhi*, Transition-Metal-Free Lactonization of sp2 C─H Bonds with CO2. Org.   Lett. 2017. 19, 396. (? Equal contribution   . Top 3 most read papers in January, 2017)

 

33.   Y.-Y. Gui,   L.-L. Liao, L. Sun, Z. Zhang, J.-H. Ye, G. Shen, Z.-P. Lu, W.-J. Zhou, D.-G. Yu*, Coupling of C(sp3)─H   Bonds with C(sp2)─O Electrophiles: Mild, General and Selective. Chem.   Comm. 2017, 53, 1192.

 

34.   J.-H. Ye,   L. Song, W.-J. Zhou, T. Ju, Z.-B. Yin, S.-S. Yan, Z. Zhang, J. Li, D.-G.   Yu*, Selective Oxytrifluoromethylation   of Allylamines with CO2.Angew.   Chem. Int. Ed. 2016, 5510022.   (Top 4 most read ACIE papers in   July, 2016)

35.   Z. Zhang,   L.-L. Liao, S.-S. Yan, L. Wang, Y.-Q. He, J.-H. Ye, J. Li, Y.-G. Zhi, D.-G. Yu*, Lactamization of sp2 C─H Bonds with CO2:   Transition-metal-free and Redox-neutral. Angew.   Chem. Int. Ed. 2016, 557068.   (扉页文章Highlighted   by SynfactsX-MOL以及《有机化学》亮点先容)

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36.   Y.-Y. Gui,   L. Sun, Z.-P. Lu, D.-G. Yu*, Photoredox sheds new light on   nickel catalysis: from carbon-carbon to carbon-heteroatom bond formation. Org. Chem.   Front. 2016, 3, 522. (From themed   collection 2015 Emerging Investigators by OCF)

 

 

37.   X. Wang?,   D.-G. Yu?, F. Glorius*, Cp*Rh(III)-Catalyzed   Arylation of sp3 C?H Bonds. Angew. Chem.   Int. Ed. 2015, 54, 10280. (? Equal   contribution)

38.   D.-G. Yu, T.   Gensch, F. de Azambuja, S. Vásquez-Céspedes, F. Glorius*, Co(III)-Catalyzed C–H Activation/Formal SN-type   Reactions: Selective and Efficient Cyanation, Halogenation, and Allylation. J. Am.   Chem. Soc. 2014, 136, 17722. (Top 3 most read JACS papers   in December, 2014).

39.   D.-G. Yu, F. de   Azambuja, T. Gensch, C. G. Daniliuc, F. Glorius*, The C–H   Activation/1,3-Diyne Strategy: Highly Selective Direct Synthesis of Diverse Bisheterocycles   by RhIII-Catalysis. Angew. Chem. Int. Ed. 2014, 53, 9650. (Highlighted   by Synfacts 2014, 10, 1023)

40.   D.-G. Yu, F. de   Azambuja, F. Glorius*, Direct Functionalization with Complete and Switchable   Positional Control: Free Phenol as A Role Model. Angew. Chem. Int. Ed.   2014, 53, 7710.   (Highlight)

41.   D.-G. Yu, F. de   Azambuja, F. Glorius*, α-MsO/TsO/Cl Ketones as Oxidized Alkyne Equivalents:   Redox-Neutral Rhodium(III)-Catalyzed C–H Activation for the Synthesis of N-Heterocycles.   Angew. Chem. Int. Ed. 2014, 53, 2754. (Top 6 most accessed   ACIE paper in Feb. 2014, Highlighted by Synfacts 2014, 10,   567.)

42.   D.-G. Yu, S. Luo,   F. Zhao, Z.-J. Shi*, Homogeneous Transition-Metal-Catalzyed C–O Bond   Activation. In Homogeneous Catalysis for Unreactive Bond Activation,   Chapter 5, Pages 347–439, 2014 (Wiley book).

43.   D.-G. Yu?, M. Suri?,   F. Glorius*, RhIII/CuII-Cocatalyzed Synthesis of 1H-Indazoles   through C?H Amidation and N?N Bond Formation. J. Am. Chem. Soc. 2013,   135, 8802. (? equal contribution, most read JACS   papers in June, 2013)

44.   Z.-J.   Shi*, D.-G. Yu, Cross-Coupling Reactions. In Comprehensive   Inorganic Chemistry II (Second Edition), Volume 6, Pages   47–77 (2013).

45.   D.-G. Yu, X. Wang,   R.-Y. Zhu, S. Luo, X.-B. Zhang, B.-Q. Wang, L. Wang, Z.-J. Shi*, Direct   Arylation/Alkylation/Magnesiation of Benzyl Alcohols in the Presence of   Grignard Reagents via Ni, Fe or Co-Catalyzed sp3 C–O Bond   Activation. J. Am. Chem. Soc. 2012, 134, 14638. (Highlighted   by Synfacts 2012, 8, 1358)

46.   D.-G. Yu, Z.-J.   Shi*, Mutual Activation: Suzuki–Miyaura Coupling through Direct Cleavage of   sp2 C–O Bond of Naphtholate. Angew. Chem. Int. Ed. 2011,   50, 7097. (Highlighted by Synfacts 2011, 10,   1111)

 

47.   D.-G. Yu, B.-J. Li, S. F. Zheng, B.-T. Guan,   B.-Q. Wang, Z.-J. Shi*, Direct Application of Phenolic Salts in Nickel-Catalyzed   Cross-Coupling with Aryl Grignard Reagents. Angew. Chem. Int.   Ed. 2010, 49, 4566. (Hot   paper, the frontpieces of Communications, highlighted by   ChemistryViews, Synfacts 2010, 9,   1051以及《有机化学》亮点先容)

48.   D.-G. Yu, B.-J.   Li, Z.-J. Shi*, Exploration of new C–O electrophiles in   cross-coupling reactions. Acc. Chem. Res. 2010, 43, 1486. (Invited   account. Top ten most-accessed articles of Acc. Chem. Res. in 2010)

49.   C.-L. Sun,   H. Li, D.-G. Yu, M. Yu, X. Zhou, X.-Y. Lu, K. Huang, S.-F.   Zheng, B.-J. Li, Z.-J. Shi*, An efficient organocatalytic method for constructing biaryls   through aromatic C–H activation.   Nature Chem. 2010, 2, 1044. (C.-L.   Sun, H. Li, and D.-G. Yu performed the experiments and analysed   the data and contributed equally to this work, highlighted by Nature Chem.,   Nature China and Synform)

50.   S. Luo?,   D.-G. Yu?, R.-Y. Zhu, X. Wang, L. Wang, Z.-J. Shi*, Fe-promoted   cross coupling of homobenzylic methyl ethers with Grignard reagents via sp3   C–O bond cleavage. Chem. Comm. 2013. 49, 7794.   (? equal contribution)

51.   D.-G. Yu, M. Yu,   B.-T. Guan, B.-J. Li, Y. Zheng, Z.-H. Wu, Z.-J. Shi*, Carbon–Carbon Formation   via Ni-Catalyzed Suzuki-Miyaura Coupling through C–CN Bond   Cleavage of Aryl Nitrile. Org. Lett. 2009, 11, 3374. (Highlighted   by Synfacts 2009, 11, 1255)

52.   施章杰* 余达刚,合成化学中的焊接技术。科技导报2010 28 29。(综述)

53.   D.-G. Yu, B.-J. Li, Z.-J. Shi*, Challenges   in C-C Bond Formation through Direct Transformations of sp2 C–H Bonds. Tetrahedron 2012,   68, 5130. (Invited account in special issue for Tetrahedron Young   Investigator Award 2012 Advances in Metal-Mediated Organic Synthesis   Zhang-Jie Shi. Cover. Top 3 hottest paper in 2012)

54.   Z.-C. Cao, D.-G. Yu, R.-Y. Zhu,   J.-B. Wei, Z.-J. Shi*, Direct Cross Coupling of Benzyl Alcohols to   Construct Diarylmethanes via Palladium Catalysis. Chem. Comm. 2015,   51, 2683.

Graphical abstract: Direct cross-coupling of benzyl alcohols to construct diarylmethanes via palladium catalysis

55.   F. Zhao, D.-G. Yu, R.-Y. Zhu,   Z.-F. Xi*, Z.-J.   Shi*, Cross-Coupling of Aryl/Alkenyl Silyl Ether with Grignard Reagents   through Nickel-Catalyzed C–O Bonds Activation. Chem. Lett. 2011, 40,   1001. (Invited research paper in Celebration for the 2010 Nobel Prize in Chemistry)

56.   B.-J. Li, D.-G. Yu, C.-L. Sun, Z.-J. Shi*, Activation of   “Inert” Alkenyl/Aryl C–O Bond and its Application in Cross-Coupling Reactions. Chem.   Eur. J. 2011, 17, 1728. (Review)

57.   K. Huang, D.-G.   Yu, S.-F. Zheng, Z.-H. Wu, L. Xu, B.-Q. Wang,   Z.-J. Shi*, Direct Borylation of   Aryl and Vinyl Carbamates via Ni-Catalyzed C–O   Activation. Chem. Eur. J.   2010, 17, 786.

58.   H. Wang, B. Beiring, D.-G. Yu, K. Collins, F. Glorius, [3]Dendralene Synthesis: Rhodium(III)-Catalyzed   Alkenyl C–H Activation and Coupling Reaction with Allenyl Carbinol Carbonate, Angew. Chem. Int. Ed. 2013, 52, 12430.

59.   F. Zhao, Y.-F. Zhang, J. Wen, D.-G. Yu, J.-B. Wei,   Z.-F. Xi*, Z.-J. Shi*, Programmed Selective sp2 C–O Bond Activation toward   Multiarylated Benzenes. Org. Lett. 2013, 15, 3230.

60.   K. Huang,   G. Li, W.-P. Huang, D.-G. Yu, Z.-J. Shi*, Arylation of α-pivaloxyl Ketones with Arylboronic   Reagents via Ni-catalyzed sp3 C–O   Activation. Chem. Commun. 2011, 47, 7224.

61.   H. Li,   C.-L. Sun, M. Yu, D.-G. Yu, B.-J.   Li, Z.-J. Shi*, The Catalytic Ability of Various Transition Metals in the   Direct Functionalization of Aromatic C–H Bonds. Chem. Eur. J. 2011, 17, 3593.

62.   C.-L. Sun,   N. Liu, B.-J. Li, D.-G. Yu, Y. Wang, Z.-J. Shi*, Pd-Catalyzed   C-H Functionalizations of O-Methyl Oximes with Arylboronic Acids. Org. Lett. 2010,   12, 184.

63.   B.-T.   Guan, X.-Y. Lu, Y. Zheng, D.-G.   Yu, T. Wu, K.-L.   Li, B.-J. Li, Z.-J. Shi*, Biaryl   Construction through Kumada Coupling with Diaryl Sulfates as One-by-One   Electrophiles under Mild Conditions. Org. Lett. 2010, 12, 396. (Highlighted by Synfacts 2010, 4, 0455)

64.   B.-T.   Guan, Y. Wang, B.-J. Li, D.-G. Yu, Z.-J. Shi*, Biaryl   Construction via Ni-Catalyzed C–O   Activation of Aryl Carboxylates. J. Am. Chem. Soc. 2008,   130, 14468. (Highlighted by Angew. Chem. Int. Ed2009, 48,   3569)

 

 

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